Simple and low-cost preparation method for highly dispersed Pd/TiO2 catalysts

Supported metal catalysts have been applied in many current industrial processes. The morphology of metal particles coated on support has been proven to affect the performance of catalysts greatly. In this study, a simple photodeposition process will be introduced to coat palladium onto titanium dioxide with an emphasis on the morphology control and size distribution of palladium particles. The effect of pH on the morphology of palladium particles was systemically investigated. It is found that the deposited palladium particles can be controlled to have narrow particle size distribution and homogeneous dispersion by a simple pH-controlled process during photodeposition. Experimental results demonstrate that the adsorption competition between OH-and PdCl42-or it s hydrolytic anions can efficiently keep local concentration of palladium ions on titanium dioxide extremely low to control the morphology of deposited palladium particles on titania. The as-prepared Pd/TiO2particles are found to be crystallitic stable indicated by TEM, XRD and XPS measurements. © 2004 Elsevier B.V. All rights reserved.